Tuesday, December 31, 2019

What Is the Strongest Acid Chemistry FAQ

What is the worlds strongest acid? Its probably not one youd guess. None of the strong acids traditionally listed in a chemistry text holds the title of Worlds Strongest Acid. The record-holder used to be fluorosulfuric acid (HFSO3), but the carborane superacids  are hundreds of times stronger than fluorosulfuric acid and over a million times stronger than concentrated sulfuric acid. The superacids readily release protons, which is a slightly different criterion for acid strength than the ability to dissociate to release a H ion (a proton). The strongest carborane superacid has the chemical structure H(CHB11Cl11).   Strong Is Different from Corrosive The carborane acids are incredible proton donors, yet they are not highly corrosive. Corrosiveness is related to the negatively-charged part of the acid. Hydrofluoric acid (HF), for example, is so corrosive it dissolves glass. The fluoride ion attacks the silicon atom in silica glass while the proton is interacting with oxygen. Even though it is highly corrosive, hydrofluoric acid is not considered to be a strong acid because it does not completely dissociate in water. The carborane acid, on the other hand, is highly stable. When it donates a hydrogen atom, a negatively charged anion left behind is sufficiently stable that it doesnt react any further. The anion is the carborane portion of the molecule. It consists of one carbon and a cluster of 11 boron atoms arranged into an icosahedron.

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